Publication Type Journal Article
Title Synthesis, crystal structure and supramolecular analysis of chlorendic acid derivatives
Authors Hemat M. Dardeer Mohamed Y. Mahgoub João Ferreira da Silva Elghareeb E. Elboray
Groups BIOMOL
Journal JOURNAL OF MOLECULAR STRUCTURE
Year 2021
Month March
Volume 1228
Number
Pages
Abstract A set of new N-substituted chlorindylimides and a chlorendic acid sodium-coordination polymer were synthesized. The synthetic chemical advantages of hexachlorobornenyl moiety and the presence of diverse substituents on the imide scaffold encouraged the exploration of the supramolecular crystal networks of all compounds based on Hirshfeld surface analysis which verified the participation of chlorine atoms in at least 70\% of the total intermolecular interactions. The predominance of Cl center dot center dot center dot Cl vs C-H center dot center dot center dot Cl interactions is based on the structural features of the incorporated imide. Unprecedentedly, the sodium 1D-polymer is composed by dimer unites of two partially deprotonated chlorendic acids with two Na(I) nodes. (C) 2020 Elsevier B.V. All rights reserved.
DOI http://dx.doi.org/10.1016/j.molstruc.2020.129458
ISBN
Publisher
Book Title
ISSN 0022-2860
EISSN 1872-8014
Conference Name
Bibtex ID ISI:000609160500003
Observations
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