| Publication Type |
Journal Article |
| Title |
SYNTHESIS AND ACTIVITY OF VANADIUM-BASED SUPPORTED CATALYSTS FOR ETHYLENE POLYMERIZATION |
| Authors |
M R Ribeiro A Deffieux M Fontanille MF Portela |
| Groups |
CATHPRO |
| Journal |
APPLIED CATALYSIS A-GENERAL |
| Year |
1993 |
| Month |
August |
| Volume |
102 |
| Number |
1 |
| Pages |
1-12 |
| Abstract |
The activity of various vanadium-based supported catalysts for the polymerization of ethene at high temperature (160-degrees) was studied. The catalytic systems were prepared by co-milling of vanadium trichloride with different metal chlorides used as supports. Their characterization was made by X-ray diffraction and B.E.T. methods. The oxidation state of vanadium in the supported catalyst after reaction with the aluminium alkyl, was determined by a potentiometric method. The effect of several parameters of catalytic systems on activity is discussed. |
| DOI |
http://dx.doi.org/10.1016/0926-860X(93)85151-E |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
0926-860X |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:A1993LU68800001 |
| Observations |
|
