| Publication Type |
Journal Article |
| Title |
Zinc(II) and cobalt(II) complexes of (3-carboxymethoxy-naphthalen-2-yloxy)-acetic acid: a structural study |
| Authors |
Anirban Karmakar Jubaraj B. Baruah R. Boomi Shankar |
| Groups |
|
| Journal |
CRYSTENGCOMM |
| Year |
2009 |
| Month |
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|
| Volume |
11 |
| Number |
5 |
| Pages |
832-840 |
| Abstract |
Different types of cyclic polynuclear complexes and one-dimensional coordination polymers of zinc(II) derived from (3-carboxymethoxy-naphthalen-2-yloxy)-acetic acid (LH2) are synthesised and characterised. The macrocyclic effect of ligand L leads to the formation of a coordination polymer having composition \[Na(2)Zn(2)(L)(2)(OH)(2)]\(n), and a binuclear zinc complex having composition [Zn(2)Na(2)(L)(2)(CH(3)COO)(2)(Pyz)(2)(MeOH)(2)] (where Pyz = pyrazole). A tetranuclear cyclic zinc(II) metallacycle with two dimethylformamide molecules in two different environments is synthesized and it has two symmetry non-equivalent cyclic molecules in its unit cell. The mononuclear complexes of zinc with L and the bidentate ligands such as 2,2 -bipyridine or 1,10-phenanthroline ancillary ligands are structurally characterised. |
| DOI |
http://dx.doi.org/10.1039/b817416d |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
1466-8033 |
| EISSN |
|
| Conference Name |
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| Bibtex ID |
ISI:000266555500020 |
| Observations |
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