| Publication Type |
Journal Article |
| Title |
Characterisation of magnesium carboxylates and their catalytic C-C bond formation reactions |
| Authors |
Bikash K. Dey Anirban Karmakar Jubaraj B. Baruah |
| Groups |
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| Journal |
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL |
| Year |
2009 |
| Month |
April |
| Volume |
303 |
| Number |
1 |
| Pages |
137-140 |
| Abstract |
Condensation reactions of aromatic aldehydes with acetone for carbon-carbon bond formation are catalysed by magnesium carboxylate complexes. Two magnesium complexes having compositions [(4-NO(2)-C(6)H(4)CO(2))(2)Mg(CH(3)OH)(4)] (1) and [(4-CH(3)-C(6)H(4)CO(2))(2)Mg(CH(3)OH)(2)(H(2)O(2))] (2) that are catalysts for such reactions are synthesized. They are prepared by reacting metallic magnesium With methanol in the presence of 4-nitrobenzoic acid and 4-methylbenzoic acid. respectively. structures of 1 and 2 are determined by X-ray crystallography. The catalytic reactions of these two complexes for carbon-carbon bond formation reactions of various aromatic aldehydes with acetone ate presented. (C) 2009 Elsevier B.V. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/j.molcata.2009.01.015 |
| ISBN |
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| Publisher |
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| Book Title |
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| ISSN |
1381-1169 |
| EISSN |
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| Conference Name |
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| Bibtex ID |
ISI:000265804600021 |
| Observations |
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