Publication Type |
Journal Article |
Title |
Coordination polymers of flexible tetracarboxylic acids with metal ions. II. Supramolecular assemblies of 5,5 -methylene- and 5,5 -(ethane-1,2-diyl)-bis(oxy)diisophthalic acid ligands with d-transition metals |
Authors |
Anirban Karmakar Israel Goldberg |
Groups |
|
Journal |
CRYSTENGCOMM |
Year |
2011 |
Month |
Notice: Undefined index: in /afs/ist.utl.pt/groups/cqe/web/tmp/templates_c/77f86a5f762542dadf50c7f7fefa96acd45c2726_0.file.paper.tpl.html.php on line 163
|
Volume |
13 |
Number |
1 |
Pages |
350-366 |
Abstract |
This report evaluates the coordination patterns of the 5,5 -methylene-bis(oxy)diisophthalic acid and 5,5 -(ethane-1,2-diyl)-bis(oxy)diisophthalic acid ligands, bearing flexible spacers between the two isophthalic acid fragments, with a series of d-metal ions. Thirteen new binary and ternary (with additional bipyridyl components) hybrid organic-inorganic coordination-driven assemblies were investigated in detail by X-ray crystallography. In most cases they exhibit polymeric architectures of three-dimensional connectivity, the formation of which is facilitated by the conformational flexibility of the ligands. |
DOI |
http://dx.doi.org/10.1039/c0ce00268b |
ISBN |
|
Publisher |
|
Book Title |
|
ISSN |
1466-8033 |
EISSN |
|
Conference Name |
|
Bibtex ID |
ISI:000285067600053 |
Observations |
|