Publication Type Journal Article
Title Coordination polymers of flexible tetracarboxylic acids with metal ions. II. Supramolecular assemblies of 5,5 -methylene- and 5,5 -(ethane-1,2-diyl)-bis(oxy)diisophthalic acid ligands with d-transition metals
Authors Anirban Karmakar Israel Goldberg
Groups
Journal CRYSTENGCOMM
Year 2011
Month
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Volume 13
Number 1
Pages 350-366
Abstract This report evaluates the coordination patterns of the 5,5 -methylene-bis(oxy)diisophthalic acid and 5,5 -(ethane-1,2-diyl)-bis(oxy)diisophthalic acid ligands, bearing flexible spacers between the two isophthalic acid fragments, with a series of d-metal ions. Thirteen new binary and ternary (with additional bipyridyl components) hybrid organic-inorganic coordination-driven assemblies were investigated in detail by X-ray crystallography. In most cases they exhibit polymeric architectures of three-dimensional connectivity, the formation of which is facilitated by the conformational flexibility of the ligands.
DOI http://dx.doi.org/10.1039/c0ce00268b
ISBN
Publisher
Book Title
ISSN 1466-8033
EISSN
Conference Name
Bibtex ID ISI:000285067600053
Observations
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