| Publication Type |
Journal Article |
| Title |
A two-dimensional metal organic network with 1,3,5-benzenetricarboxylate and cobalt (II) ions: synthesis, structure and topology |
| Authors |
Anirban Karmakar Clive L. Oliver |
| Groups |
|
| Journal |
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS |
| Year |
2013 |
| Month |
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|
| Volume |
228 |
| Number |
7 |
| Pages |
330-334 |
| Abstract |
We herein report the synthesis and structure of a two dimensional (2D) metal-organic coordination polymer (or metal-organic network) which extends in two dimensions via Co2+ and 1,3,5-benzenetricarboxylate ions. The hydrothermal reaction of (2R,2 R,2 R)-2,2 ,2 -(benzenetricarbonyltris(azanediyl))tripropanoic acid (parent ligand) with cobalt nitrate in the presence of pyridine lead to the decomposition of the parent ligand producing 1,3,5-benzenetricarboxylate, which in turn reacted with cobalt ions to afford a 2D network [Co-1.5(BTC3-) center dot (pyridine)(3) center dot (H2O)](H2O)(0.26) center dot (MeOH) (1). This network was characterized by single crystal X-ray diffraction and IR spectroscopy. The topological study indicated that the framework is a 3,4-connected binodal net. |
| DOI |
http://dx.doi.org/10.1524/zkri.2013.1610 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
2194-4946 |
| EISSN |
2196-7105 |
| Conference Name |
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| Bibtex ID |
ISI:000322976200005 |
| Observations |
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