| Abstract |
The reaction of trans-[PtCl2(Me2SO)(2)] with 2 equivs of 1,3,5-triaza-7-phosphaadamantane (PTA) in MeNO2 at RT furnished cis-[PtCl2(PTA)(2)] (1) in 87\% isolated yield. Corresponding reaction of K-2[PtCl4] with 1 equiv, of PTA in aqueous EtOH at RT led to [PtCl(PTA)(3)]Cl (2) in 84\% isolated yield. Complexes 1 and 2 were characterized by elemental analyses (C, H, N), HR-ESI+/—MS, IR, H-1 and P-31\H-1\ NMR spectroscopic techniques, and by single-crystal X-ray diffraction for 1. (C) 2014 Elsevier B.V. All rights reserved. |
