| Abstract |
The structural evolution of a metallocenic syndiotactic poly(propylene), sPP, with time has been studied. Due to the low syndiotactic content, the analyzed sPP sample can be easily quenched to a completely amorphous state. This amorphous sample, when left at room temperature is able to crystallize at relatively long times. The degree of crystallinity, as a function of time, has been analyzed by X-ray diffraction and DSC. The DSC melting curves show the presence of a very important low-temperature endotherm, besides the main melting peak. Real-time variable-temperature synchrotron experiments have been performed in order to analyze the origin of the two melting peaks. They seem to arise from the melting of two populations of sPP crystals with different size and/or perfection, rather than from the melting of different polymorphs. The changes in the crystalline regions are accompanied by important variations in the mechanical behavior, as revealed by DMTA and microhardness (MH) measurements. In addition, the sPP crystallization has been analyzed by MH measurements, showing the importance that a relative low crystallinity has on the stiffness of a polymeric material at temperatures above T-g. On the other hand, the kinetics of the enthalpic recovery of quenched amorphous sPP specimens has been analyzed by DSC with temperature modulation. It was found that this enthalpic relaxation can be described by the KWW model, and. the relaxation times and shape parameters at three different aging temperatures have been determined, with the corresponding apparent activation energy of this process. |
