| Publication Type |
Journal Article |
| Title |
Ansa-bridged eta-cyclopentadienyl imido and amido derivatives of titanium, zirconium and molybdenum |
| Authors |
Pedro T. Gomes MLH Green Ana M. Martins |
| Groups |
IOARC |
| Journal |
JOURNAL OF ORGANOMETALLIC CHEMISTRY |
| Year |
1998 |
| Month |
January |
| Volume |
551 |
| Number |
1 |
| Pages |
133-138 |
| Abstract |
An improved synthesis of the ligand precursor \[C5H4(SiMe3)](CH2)(3)N(SiMe3)(2)) is described. It has been used to prepare the compounds \Ti[eta:sigma-C5H4(CH2)(3)N(SiMe3)]Cl-2), \Ti[eta-C5H4(CH2)(3)(mu-N)C-l\(2), \Zr[eta:sigma-C5H4(CH2)(3)N(SiMe3)](SMe2)Cl-2\, \Zr[eta:sigma-C5H4(CH2)(3)N(SiMe3)]Cl-2\ and (Mo[eta:sigma-C5H4(CH2)(3)N(SiMe3)](PMe3)Cl-2\. The zirconium compounds together with methylaluminoxane act as catalysts for ethylene and propylene polymerisation. (C) 1998 Elsevier Science S.A. |
| DOI |
http://dx.doi.org/10.1016/S0022-328X(97)00516-0 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
0022-328X |
| EISSN |
|
| Conference Name |
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| Bibtex ID |
ISI:000073410100016 |
| Observations |
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