Publication Type |
Journal Article |
Title |
Accessing Two-Coordinate Zn-II Organocations by NHC Coordination: Synthesis, Structure, and Use as pi-Lewis Acids in Alkene, Alkyne, and CO2 Hydrosilylation |
Authors |
David Specklin Frederic Hild Christophe Fliedel Christophe Gourlaouen Luis F. Veiros Samuel Dagorne |
Groups |
IOARC |
Journal |
CHEMISTRY-A EUROPEAN JOURNAL |
Year |
2017 |
Month |
November |
Volume |
23 |
Number |
63 |
Pages |
15908-15912 |
Abstract |
Discrete two-coordinate Zn-II organocations of the type (NHC)Zn-R+ are reported, thanks to NHC stabilization. In preliminary reactivity studies, such entities, which are direct cationic analogues of long-known ZnR2 species, act as effective and tunable pi-Lewis acid catalysts in alkene, alkyne, and CO2 hydrosilylation. |
DOI |
http://dx.doi.org/10.1002/chem.201704382 |
ISBN |
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Publisher |
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Book Title |
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ISSN |
0947-6539 |
EISSN |
1521-3765 |
Conference Name |
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Bibtex ID |
ISI:000414990400012 |
Observations |
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