Publication Type |
Journal Article |
Title |
Oxidation of saturated hydrocarbons to alkyl hydroperoxides by a H2O2/titanosilicalite-1/NaOH/MeCN system |
Authors |
Georgiy B. Shul'pin M Kirillova Tawan Sooknoi Armando J.L. Pombeiro |
Groups |
BioMol CCC |
Journal |
CATALYSIS LETTERS |
Year |
2008 |
Month |
June |
Volume |
123 |
Number |
1 |
Pages |
135-141 |
Abstract |
Hydrogen peroxide oxidizes alkanes at room temperature to produce the corresponding alkyl hydroperoxides in the presence of titanosilicalite-1, NaOH and acetonitrile. The reaction proceeds with low regio- and bond-selectivity and its mechanism apparently involves the formation of hydroxyl radicals. |
DOI |
http://dx.doi.org/10.1007/s10562-008-9406-8 |
ISBN |
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Publisher |
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Book Title |
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ISSN |
1011-372X |
EISSN |
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Conference Name |
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Bibtex ID |
ISI:000256081700021 |
Observations |
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