Publication Type Journal Article
Title Structural characterisation of flavonoids and flavonoid-O-glycosides extracted from Genista tenera by fast-atom bombardment tandem mass spectrometry
Authors Carlos M. Borges P Martinho Alice Martins Amélia P. Rauter MAA Ferreira
Groups HC
Journal RAPID COMMUNICATIONS IN MASS SPECTROMETRY
Year 2001
Month
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Volume 15
Number 18
Pages 1760-1767
Abstract Genista tenera is a plant native to the Madeira Island (Portugal). From the ethanol extract of its powdered aerial parts, two flavones, three isoflavones and one 7-O-glacosyl isoflavone were isolated. A mass spectrometric study of these compounds was performed using liquid secondary ion mass spectrometry (LSIMS) in combination with high-energy collision-induced dissociation (CID) and tandem mass spectrometry (MS/MS). Characteristic fragmentation patterns were observed in all the investigated compounds; the loss of small neutral species from the protonated molecules was useful for identifying the presence of specific functional groups in the A- and B-rings. In order to help to establish the proposed structures, NMR and UV studies were also performed. Copyright (C) 2001 John Wiley \& Sons, Ltd.
DOI http://dx.doi.org/10.1002/rcm.436
ISBN
Publisher
Book Title
ISSN 0951-4198
EISSN
Conference Name
Bibtex ID ISI:000171017900016
Observations
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