Publication Type |
Journal Article |
Title |
Effect of the pressure on the viscosities of ionic liquids: Experimental values for 1-ethyl-3-methylimidazolium ethylsulfate and two bis(trifluoromethyl-sulfonyl)imide salts |
Authors |
Felix M. Gacino X. Paredes Maria J. P. Comunas Josefa Fernandez |
Groups |
MTFT |
Journal |
JOURNAL OF CHEMICAL THERMODYNAMICS |
Year |
2012 |
Month |
November |
Volume |
54 |
Number |
|
Pages |
302-309 |
Abstract |
A new falling-body viscometer has been implemented to measure viscosity of liquids in a temperature range from (313.15 to 363.15) K at pressures up to 150 MPa. The accuracy of the viscometer was verified after comparing experimental results of squalane with previous literature data finding an average absolute deviation lower than 1.5\%. With this device, we have measured viscosity values for three ionic liquids: 1-ethyl-3-methylimidazolium ethylsulfate, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide and 1-(2-methoxyethyl)-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide within the temperature and pressure ranges noted above. The experimental values were correlated as a function of temperature and pressure with four different equations. In addition, we have analysed the pressure-viscosity derived properties for these fluids and for other five ionic liquids using literature values. (C) 2012 Elsevier Ltd. All rights reserved. |
DOI |
http://dx.doi.org/10.1016/j.jct.2012.05.007 |
ISBN |
|
Publisher |
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Book Title |
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ISSN |
0021-9614 |
EISSN |
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Conference Name |
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Bibtex ID |
ISI:000306491500041 |
Observations |
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