| Publication Type |
Journal Article |
| Title |
X-ray characterization of an unusual product obtained from [VO(Sal-Phe)(H2O)] in H2O/pyridine solutions |
| Authors |
A Bernalte FJG Barros Isabel Cavaco J.C. Pessoa RD Gillard FJ Higes Ana Isabel Tomaz |
| Groups |
BIOIN |
| Journal |
POLYHEDRON |
| Year |
1998 |
| Month |
Notice: Undefined index: in /afs/ist.utl.pt/groups/cqe/web/tmp/templates_c/77f86a5f762542dadf50c7f7fefa96acd45c2726_0.file.paper.tpl.html.php on line 163
|
| Volume |
17 |
| Number |
19 |
| Pages |
3269-3274 |
| Abstract |
A vanadium(V) dimer [\VO2(py)(2)\(2)(mu-C2O4)] 1, has been isolated from a solution of [VO(sal-Phe)(H2O)] 2 (sal-Phe = N-salicylidene-L-phenylalaninate) in H2O/pyridine. Its crystal and molecular structure has been determined by X-ray diffraction analysis, the oxalate acting as a symmetrical bis(chelating) bridge. Possible mechanisms for the formation of oxalate are briefly discussed. (C) 1998 Elsevier Science Ltd. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/S0277-5387(98)00105-3 |
| ISBN |
|
| Publisher |
PERGAMON-ELSEVIER SCIENCE LTD |
| Book Title |
|
| ISSN |
0277-5387 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000076707100004 |
| Observations |
|
