| Publication Type |
Journal Article |
| Title |
New studies on the chemical oxidation of bis(eta(5)-cyclopentadienyl)dithiolatemolybdenum(IV) complexes. Crystal structures of [(Mo(eta(5)-C5H5)(2)S(C6H4-o-S)C6H5)][BF4] and [Mo(eta(5)-C5H5)(2)(SC6H5)(2)] |
| Authors |
A. R. Dias M. Helena Garcia M.Fatima M.Piedade MAAFD CARRONDO |
| Groups |
|
| Journal |
JOURNAL OF ORGANOMETALLIC CHEMISTRY |
| Year |
2001 |
| Month |
August |
| Volume |
632 |
| Number |
1 |
| Pages |
107-112 |
| Abstract |
A new pattern on the reactivity of bis(eta (5)-cyclopentadienyl)dithiolatemolybdenum(IV) metalloligands was found upon study of several chemical reactions involving the redox behaviour of these compounds. Chemical oxidants, such as Ag+ and NO, led to very different monochelate and binuclear final products. The molecular structure of the new compound which contains the metalloring cation [Mo(eta (5)-C5H5)(2)S(C6H4-o-SC6H5)](+) was characterised by single-crystal X-ray diffraction. and for comparison, also the molecular structure of the parent compound [Mo(-eta (5)-C5H5)(2)(SPh)(2)] is also presented and discussed. (C) 2001 Elsevier Science B.V. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/S0022-328X(01)01038-5 |
| ISBN |
|
| Publisher |
ELSEVIER SCIENCE SA |
| Book Title |
|
| ISSN |
0022-328X |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000171103200013 |
| Observations |
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