Publication Type |
Journal Article |
Title |
Water-soluble and stable dinitrogen phosphine complexes trans-[ReCl(N-2)(PTA-H)(n)(PTA)(4-n)](n+) (n=0-4), the first with 1,3,5-triaza-7-phosphaadamantane |
Authors |
P. Smolenski Armando J.L. Pombeiro |
Groups |
CCC |
Journal |
DALTON TRANSACTIONS |
Year |
2008 |
Month |
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Volume |
|
Number |
1 |
Pages |
87-91 |
Abstract |
The first dinitrogen complexes with the hydrosoluble PTA ligand, or its protonated form PTA-H, trans-[ReCl(N-2)(PTA-H) n(PTA)(4-n)](n+) (n = 0-4), are prepared, shown to be soluble and stable in water, interconvertible by stepwise protonation/deprotonation and to form, upon N-2 loss, the corresponding penta-coordinate compounds. Dinitrogen displacement by CO affords trans-[ReCl(CO)(PTA)(4)]. |
DOI |
http://dx.doi.org/10.1039/b712360d |
ISBN |
|
Publisher |
ROYAL SOC CHEMISTRY |
Book Title |
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ISSN |
1477-9226 |
EISSN |
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Conference Name |
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Bibtex ID |
ISI:000251673200015 |
Observations |
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