Publication Type Journal Article
Title 5-Phenyl-3,4-dihydro-2H-pyrrole: the first example of a planar monosubstituted 1-pyrroline
Authors Clara S. B. Gomes Claudia A. Figueira Pedro T. Gomes M. Teresa Duarte
Groups IOARC BioMol
Journal ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Year 2008
Month June
Volume 64
Number 6
Pages O303-O305
Abstract In the title compound, C10H11N, the molecules assemble as pseudo-dimers through pi-pi interactions, each dimer being rotated by about 90 degrees with respect to its neighbours. The relative positioning of the dimers and C-H center dot center dot center dot pi interactions give, when seen along a, a supramolecular zigzag arrangement. The compound contains a planar pyrroline ring and, as a whole, its molecular conformation is also planar, which represents the first example of a totally planar 2-substituted 1-pyrroline and the simplest ever reported by X-ray diffraction.
DOI http://dx.doi.org/10.1107/S0108270108011360
ISBN
Publisher WILEY-BLACKWELL
Book Title
ISSN 0108-2701
EISSN
Conference Name
Bibtex ID ISI:000256468200008
Observations
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