| Abstract |
The solubility of xenon in liquid cyclopenta tie has been studied experimentally and theoretically. Measurements of the solubility of xenon in liquid cyclopentane are reported as a function of temperature from 254.60 K to 313.66 K. The imprecision of the experimental data is less than 0.3\%. The thermodynamic function of salvation of xenon in cyclopentane, such as the standard Gibbs energy, enthalpy, entropy and heat capacity of solvation, have been calculated from the temperature dependence of Henry s law coefficients. The results provide further information about the differences between the xenon + cycloalkanes and the xenon + n-alkane interactions. In particular, interaction enthalpies between xenon and CH(2) groups in n-alkanes and cycloalkanes have been estimated and compared. Using a version of the soft-SAFE approach developed to model cyclic molecules, we were able to reproduce the experimental solubility for xenon in cyclopentane using simple Lorentz-Berthelot rules to describe the unlike interaction. (c) 2011 Elsevier B.V. All rights reserved. |
