Publication Type |
Journal Article |
Title |
Water-Soluble Cobalt(II) and Copper(II) Complexes of 3-(5-Chloro-2-hydroxy-3-sulfophenylhydrazo)pentane-2,4-dione as Building Blocks for 3D Supramolecular Networks and Catalysts for TEMPO-Mediated Aerobic Oxidation of Benzylic Alcohols |
Authors |
Maximilian N. Kopylovich Kamran T. Mahmudov Matti Haukka Pawel J. Figiel Archana Mizar J A L Silva Armando J.L. Pombeiro |
Groups |
CCC BIOIN |
Journal |
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY |
Year |
2011 |
Month |
September |
Volume |
|
Number |
27 |
Pages |
4175-4181 |
Abstract |
A new water-soluble beta-diketone azo derivative - 3-(5-chloro- 2-hydroxy-3-sulfophenylhydrazo)pentane-2,4-dione (H3L, 1) - was synthesized and found to be stable in DMSO solution and in the solid state in the hydrazo tautomeric form. Its water-soluble complexes [Co(HL)(en)(H2O)]center dot 4H(2)O (3) and the zwitterionic [Cu(L)(Hen)(H2O)] (4)(r) with buffering properties, were prepared by reaction of cobalt(II) and copper(II) nitrates with the ethylenediammonium (H(2)en) salt of 1, (H(2)en)(HL) (2). In the formation of 3 and 4, 1 is a chelating ligand, and a crucial synthetic and structural role is played by en, allowing the organization of water-soluble assemblies and influencing the overall 3D supramolecular arrangement. Compound 3 is the first cobalt complex with an azo derivative of a beta-diketone. Complex 4 acts as catalyst precursor for the aerobic TEMPO-mediated selective oxidation of benzylic alcohols to the corresponding aldehydes in aqueous media. |
DOI |
http://dx.doi.org/10.1002/ejic.201100348 |
ISBN |
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Publisher |
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Book Title |
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ISSN |
1434-1948 |
EISSN |
1099-0682 |
Conference Name |
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Bibtex ID |
ISI:000296143500007 |
Observations |
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