Publication Type |
Journal Article |
Title |
Cyclam Functionalization through Isocyanate Insertion in Zr-N Bonds |
Authors |
Luis G. Alves Ana M. Martins |
Groups |
IOARC |
Journal |
INORGANIC CHEMISTRY |
Year |
2012 |
Month |
January |
Volume |
51 |
Number |
1 |
Pages |
10-12 |
Abstract |
The insertion of isocyanates in (Bn(2)Cyclam)ZrX2 is regioselective; (Bn(2)Cyclam)Zr(OR)(2) produces urea-like moieties by the insertion of RN=C=O in the Zr-N-amido bonds of the cyclam ring. Depending on the bulkiness of the isocyanate R groups, O- and N-bound ureates are formed. (Bn(2)Cyclam)Zr((NHBu)-Bu-t)(2) reacts with MesN=C=O at the terminal Zr-N bonds. |
DOI |
http://dx.doi.org/10.1021/ic201750y |
ISBN |
|
Publisher |
|
Book Title |
|
ISSN |
0020-1669 |
EISSN |
|
Conference Name |
|
Bibtex ID |
ISI:000298712000004 |
Observations |
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