| Publication Type |
Journal Article |
| Title |
A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst |
| Authors |
Manas Sutradhar M Kirillova M. Fátima C. Guedes da Silva L.M.D.R.S. Martins Armando J.L. Pombeiro |
| Groups |
CCC BioMol |
| Journal |
INORGANIC CHEMISTRY |
| Year |
2012 |
| Month |
November |
| Volume |
51 |
| Number |
21 |
| Pages |
11229-11231 |
| Abstract |
The new hexanuclear mixed-valence vanadium complex [V3O3(OEt)(ashz)(2)(mu-OEt)](2) (1) with an N,O-donor ligand is reported. It acts as a highly efficient catalyst toward alkane oxidations by aqueous H2O2. Remarkably, high turnover numbers up to 25000 with product yields of up to 27\% (based on alkane) stand for one of the most active systems for such reactions. |
| DOI |
http://dx.doi.org/10.1021/ic3017062 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
0020-1669 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000313220200007 |
| Observations |
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