| Publication Type |
Journal Article |
| Title |
Inorganic-organic hybrid double sulfates as catalysts of the diastereoselective nitroaldol reaction |
| Authors |
Omar Kammoun Walid Rekik Thierry Bataille Kamran T. Mahmudov Maximilian N. Kopylovich Houcine Naili |
| Groups |
CCC |
| Journal |
JOURNAL OF ORGANOMETALLIC CHEMISTRY |
| Year |
2013 |
| Month |
October |
| Volume |
741 |
| Number |
|
| Pages |
136-140 |
| Abstract |
Bis(1-phenylethanaminium) disulfatotetraaquazincate(II) dihydrate (C8H12N)(2)[Zn(H2O)(4)(SO4)(2)]center dot 2H(2)O (1), bis(1H-benzo[d]imidazolium) hexaaquazinc(II) bis(sulfate) tetrahydrate (C7H7N2)(2)[Zn(H2O)(6)](SO4)(2)center dot 4H(2)O (2) and bis(2-methyl-1H-imidazolium) hexaaquazinc(II) bis(sulfate) dihydrate (C4H7N2)(2)[Zn(H2O)(6)](SO4)(2)center dot 2H(2)O (3) have been synthesized and fully structurally characterized including single-crystal X-ray diffraction analysis. 1-3 are organically templated hybrid layered materials comprising aquazinc(II) and aminium cations and sulfate anions. 1-3 are effective catalysts in the asymmetric Henry reaction; 1 being the most efficient one (yields up to 85\% and threo/erythro diastereoselectivity up to 89:11). (C) 2013 Elsevier B.V. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/j.jorganchem.2013.05.028 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
0022-328X |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000322932700021 |
| Observations |
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