Publication Type Journal Article
Title Reduced Graphene Oxide Composite with Oxidizable Manganese/Cobalt Mixed Oxide for p-Cresol Oxidation by Using Molecular Oxygen
Authors Ajay Jha Sagar H. Patil Bhanu P. Solanki A.P.C. Ribeiro CA Nieto de Castro Kashinath R. Patil Alberto Coronas Chandrashekhar V. Rode
Groups CCC
Journal CHEMPLUSCHEM
Year 2015
Month July
Volume 80
Number 7
Pages 1164-1169
Abstract A composite of graphene oxide (GO) with mixed oxide (MnCo) was prepared by using a solvothermal method. During the synthesis, both the reduction of GO and growth of metal oxides took place simultaneously. The as-prepared composite material was highly selective for the liquid-phase oxidation of p-cresol to form p-hydroxybenzaldehyde in 71\% yield within 1h. The composite material was characterised by SEM, X-ray photoelectron spectroscopy, high-resolution TEM and cyclic voltammetry (CV). A CV study revealed that the increase in the redox potential of the mixed oxide after being supported on GO, led to its higher activity of the catalyst for the oxidation reaction. The stability of the catalyst under the reaction conditions was studied by its successful reuse in three cycles.
DOI http://dx.doi.org/10.1002/cplu.201500053
ISBN
Publisher WILEY-V C H VERLAG GMBH
Book Title
ISSN 2192-6506
EISSN
Conference Name
Bibtex ID ISI:000357617800013
Observations
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