Publication Type |
Journal Article |
Title |
How similar is similar? Exploring the binary and ternary solid solution landscapes of p-methyl/chloro/bromo-benzyl alcohols |
Authors |
A. K. S. Romasanta D. Braga M. Teresa Duarte F. Grepioni |
Groups |
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Journal |
CRYSTENGCOMM |
Year |
2017 |
Month |
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|
Volume |
19 |
Number |
4 |
Pages |
653-660 |
Abstract |
New binary and ternary solid solutions formed by p-chlorobenzyl alcohol (p-ClBA), p-bromobenzyl alcohol (p-BrBA) and their quasi-isostructural compound p-methylbenzyl alcohol (p-MeBA) have been prepared and characterized by DSC and powder X-ray diffraction. The binary and ternary solid solutions were synthesized by co-melting of p-MeBA/p-ClBA, p-MeBA/p-BrBA and p-ClBA/p-BrBA and by co-melting of p-MeBA/p-ClBA/p-BrBA in various molar ratios. By varying the relative concentrations, it has been possible to observe the consequent variations of the melting points of the solid solutions. For the binary 1:1 p-MeBA/p-BrBA and p-ClBA/p-BrBA compounds, single crystals were grown from solution and their structures were investigated by X-ray diffraction. |
DOI |
http://dx.doi.org/10.1039/c6ce02282k |
ISBN |
|
Publisher |
ROYAL SOC CHEMISTRY |
Book Title |
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ISSN |
1466-8033 |
EISSN |
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Conference Name |
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Bibtex ID |
ISI:000395439700008 |
Observations |
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