| Publication Type |
Journal Article |
| Title |
[Ti(C5Me3RSiMe2NBut)Cl-2] (R = alkyl or aryl) complexes as catalysts for ethylene polymerization |
| Authors |
M Fernanda NN Carvalho K Mach A. R. Dias JF Mano M. Mercês Marques AM Soares Armando J.L. Pombeiro |
| Groups |
|
| Journal |
INORGANIC CHEMISTRY COMMUNICATIONS |
| Year |
2003 |
| Month |
April |
| Volume |
6 |
| Number |
4 |
| Pages |
331-334 |
| Abstract |
[Ti(C5Me3RSiMe2NBut)Cl-2] (R=alkyl or aryl) complexes in combination with methylaluminoxane were found to be highly efficient catalysts towards ethylene polymerization. The species with aromatic R groups display higher activity than those with aliphatic ones. This tendency could not be correlated with the electronic properties of the complexes that were evaluated by cyclic voltammetry. The polyethylenes obtained in the catalytic processes were characterized by H-1 NMR and DSC. (C) 2002 Elsevier Science B.V. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/S1387-7003(02)00748-7 |
| ISBN |
|
| Publisher |
ELSEVIER SCIENCE BV |
| Book Title |
|
| ISSN |
1387-7003 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000180981600001 |
| Observations |
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