Publication Type |
Journal Article |
Title |
Camphor-palladium complexes as catalysts for cyclization of alkynes |
Authors |
M Fernanda NN Carvalho M. Teresa Duarte R Herrmann |
Groups |
|
Journal |
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS |
Year |
2006 |
Month |
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|
Volume |
71 |
Number |
3 |
Pages |
302-310 |
Abstract |
Catalytic properties of the camphor-derived complexes trans-[PdCl2(L1)(2)], R = Me2N (1), i-Pr (3), C6H5 (4), in PhC equivalent to CMe cyclotrimerization are highly dependent on the characteristics of the R group. Their activity decreases in the order 1 > 3 > 4. The effects of geometric and/or electronic parameters on the catalytic activity of the complexes are evaluated on the basis of X-ray and electrochemical data. |
DOI |
http://dx.doi.org/10.1135/cccc20060302 |
ISBN |
|
Publisher |
INST ORGANIC CHEM AND BIOCHEM |
Book Title |
|
ISSN |
0010-0765 |
EISSN |
|
Conference Name |
|
Bibtex ID |
ISI:000236938000003 |
Observations |
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