Publication Type |
Journal Article |
Title |
SELECTIVE HYDRATION OF FERROCENYLETHYNE MEDIATED BY A PALLADIUM COMPLEX WITH A CAMPHORHYDRAZONE LIGAND |
Authors |
Jiri Tauchman M Fernanda NN Carvalho Petr Stepnicka |
Groups |
BioMol |
Journal |
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS |
Year |
2011 |
Month |
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|
Volume |
76 |
Number |
11 |
Pages |
1277-1283 |
Abstract |
Complex [PdCl2L2], where L is a camphor hydrazone ligand, (1R, 4S)-1,7,7-trimethyl-3-( 2,2-dimethylhydrazone)-bicyclo[2.2.1]heptane-2,3-dione, efficiently promotes Markovnikov hydration of ethynylferrocene to acetylferrocene in aqueous methanol at room temperature. 1-Ferrocenylprop-1-yne and simple organic alkynes such as 1-octyne or ethynylbenzenes are not affected or polymerize under the reaction conditions. |
DOI |
http://dx.doi.org/10.1135/cccc2011130 |
ISBN |
|
Publisher |
INST ORGANIC CHEM AND BIOCHEM |
Book Title |
|
ISSN |
0010-0765 |
EISSN |
1212-6950 |
Conference Name |
|
Bibtex ID |
ISI:000298004700001 |
Observations |
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