| Publication Type |
Journal Article |
| Title |
New diamondoid-like[Cu3B(mu-O)(6)] core self-assembled from Bis-Tris biobuffer for mild hydrocarboxylation of alkanes to carboxylic acids |
| Authors |
A Kirillov Yauhen Yu. Karabach M Kirillova Matti Haukka Armando J.L. Pombeiro |
| Groups |
BioMol CCC |
| Journal |
DALTON TRANSACTIONS |
| Year |
2011 |
| Month |
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|
| Volume |
40 |
| Number |
24 |
| Pages |
6378-6381 |
| Abstract |
The new tricopper(II) complex [Cu-3(mu(3)-BO)(H3L)(3)][BF4]center dot 2H(2)O (1) with an unprecedented diamondoid-like [Cu3B(mu-O)(6)] core has been easily generated by self-assembly in an aqueous medium from Cu(NO3)(2), NaBF4, NaOH and Bis-Tris (H5L) biobuffer, (HOCH2)(3)CN(CH2CH2OH)(2). Compound 1 efficiently promotes the mild single-pot hydrocarboxylation, by CO and H2O, of various linear and cyclic C-n (n = 2-8) alkanes into the corresponding Cn+1 carboxylic acids. |
| DOI |
http://dx.doi.org/10.1039/c1dt10421g |
| ISBN |
|
| Publisher |
ROYAL SOC CHEMISTRY |
| Book Title |
|
| ISSN |
1477-9226 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000291385700008 |
| Observations |
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