| Publication Type |
Journal Article |
| Title |
New silver BioMOFs driven by 1,3,5-triaza-7-phosphaadamantane-7-sulfide (PTA=S): synthesis, topological analysis and antimicrobial activity |
| Authors |
Sabina W. Jaros P. Smolenski M. Fátima C. Guedes da Silva Magdalena Florek Jaroslaw Krol Zdzislaw Staroniewicz Armando J.L. Pombeiro A Kirillov |
| Groups |
CCC BioMol |
| Journal |
CRYSTENGCOMM |
| Year |
2013 |
| Month |
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|
| Volume |
15 |
| Number |
40 |
| Pages |
8060-8064 |
| Abstract |
Two new bioactive silver-organic frameworks [Ag(mu(3)-PTA=S)](n)(NO3)(n)center dot nH(2)O (1) and [Ag-4(mu(4)-PTA=S)(mu(5)-PTA=S)(mu(2)-SO4)(2)(H2O)(2)](n)center dot 2nH(2)O (2) were easily assembled, thus opening up the application of PTA=S as a versatile N,S-building block in the crystal engineering of MOFs. The obtained products reveal infinite 3D networks driven by multiply bridging PTA=S spacers that adopt unprecedented N2S-coordination modes. The topological analysis of 1 discloses an uninodal 3-connected net with the srs (SrSi2) topology, whereas 2 features a pentanodal 3,4,5-connected net with a hitherto undocumented topology. Apart from representing the first MOFs derived from PTA=S, the compounds 1 and 2 display notable antibacterial and antifungal activities. |
| DOI |
http://dx.doi.org/10.1039/c3ce40913a |
| ISBN |
|
| Publisher |
ROYAL SOC CHEMISTRY |
| Book Title |
|
| ISSN |
1466-8033 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000324885100001 |
| Observations |
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