| Abstract |
A group of new mononuclear boron chelate compounds [BPh2\kappa N-2,N -5-R-NC4H2-2-C(H)-N-Ar\] (R = Ar = C(6)H(5)7; R = C6H5, Ar = 2,6-iPr(2)C(6)H(3)8; R = Anthracen-9-yl (Anthr), Ar = C(6)H(5)9; R = Anthr, Ar = 2,6-iPr(2)C(6)H(3)10) were synthesized via the reaction of B(C6H5)(3) with the corresponding 5-substituted 2-(N-arylformimino)pyrrole ligand precursors 3-6. These complexes were prepared in order to evaluate the luminescence potential derived from the substitution of the position 5 of the pyrrolyl ring with an aromatic group. Compounds 7-10 were photophysically characterized in solution and in the solid state. The 5-phenyl-2-iminopyrrolyl-BPh2 complexes 7 and 8 are blue emitters and have enhanced photoluminescence quantum yields in the solid state (phi(PL)) up to 0.95, whereas the 5-anthracenyl derivatives 9 and 10 have green-bluish fluorescence and a phi(PL) of 0.49 and 0.24, respectively. DFT and TDDFT studies were performed, considering the effect of solvent and dispersion, in order to show how the geometries of compounds 7-10 changed from the ground to the excited state, to assign electronic transitions, and to rationalize the observed luminescence. These materials were applied in organic light-emitting diodes (OLEDs), with various device structures, the best showing an external quantum efficiency of 2.75\% together with a high luminance of 23 530 cd m(-2). |
