Publication Type Journal Article
Title Bis\mu(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato\bis(mu(3)-N-me thyl-2,2 -azanediyldiethanolato)tetrakis(thiocyanatato-kappa N)dichromium(III)dimanganese(II) dimethylformamide tetrasolvate
Authors Valentyna V. Semenaka Oksana V. Nesterova Volodymyr N. Kokozay Roman I. Zubatyuk Oleg V. Shishkin
Groups
Journal ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Year 2011
Month December
Volume 67
Number 12
Pages M1864-U1806
Abstract The heterometallic title complex, [Cr2Mn2(C5H11NO2)(2)-(C5H12NO2)(2)(NCS)(4)]center dot 4C(3)H(7)NO, was prepared using manganese powder, Reineckes salt, ammonium thiocyanate and a non-aqueous solution of N-methyldiethanolamine in air. The centrosymmetric molecular structure of the complex is based on a tetranuclear \Mn2Cr2(mu-O)(6)\ core. The tetranuclear complex molecule and the two uncoordinated dimethylformamide molecules are linked by O-H center dot center dot center dot O hydrogen bonds, while the two other molecules of dimethylformamide do not participate in hydrogen bonding.
DOI http://dx.doi.org/10.1107/S1600536811049336
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Book Title
ISSN 1600-5368
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Bibtex ID ISI:000298795500150
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