Publication Type |
Journal Article |
Title |
Bis\mu(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato\bis(mu(3)-N-me thyl-2,2 -azanediyldiethanolato)tetrakis(thiocyanatato-kappa N)dichromium(III)dimanganese(II) dimethylformamide tetrasolvate |
Authors |
Valentyna V. Semenaka Oksana V. Nesterova Volodymyr N. Kokozay Roman I. Zubatyuk Oleg V. Shishkin |
Groups |
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Journal |
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
Year |
2011 |
Month |
December |
Volume |
67 |
Number |
12 |
Pages |
M1864-U1806 |
Abstract |
The heterometallic title complex, [Cr2Mn2(C5H11NO2)(2)-(C5H12NO2)(2)(NCS)(4)]center dot 4C(3)H(7)NO, was prepared using manganese powder, Reineckes salt, ammonium thiocyanate and a non-aqueous solution of N-methyldiethanolamine in air. The centrosymmetric molecular structure of the complex is based on a tetranuclear \Mn2Cr2(mu-O)(6)\ core. The tetranuclear complex molecule and the two uncoordinated dimethylformamide molecules are linked by O-H center dot center dot center dot O hydrogen bonds, while the two other molecules of dimethylformamide do not participate in hydrogen bonding. |
DOI |
http://dx.doi.org/10.1107/S1600536811049336 |
ISBN |
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Publisher |
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Book Title |
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ISSN |
1600-5368 |
EISSN |
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Conference Name |
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Bibtex ID |
ISI:000298795500150 |
Observations |
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