Publication Type Journal Article
Title Mononuclear and tetranuclear Fe(III) complexes with two different types of N, O donor Schiff base ligands
Authors Manas Sutradhar Tannistha Roy Barman Michael G. B. Drew Eva Rentschler
Groups
Journal JOURNAL OF MOLECULAR STRUCTURE
Year 2013
Month June
Volume 1041
Number
Pages 44-49
Abstract A mononuclear Fe(III) complex of a tetradentate N2O2 donor Schiff base ligand derived from 3-ethoxysalicaldehyde and ethylenediamine has been reported. In addition two tetranuclear Fe(III) complexes with discrete Fe-4(III)(mu(4)-0) cores have been synthesized and characterized using two Schiff base ligands (H2L1-2) derived from two different aromatic acid hydrazides and diacetyl monoxime. The mononuclear Fe(III) and one of the tetranuclear Fe(III) complexes have been structurally characterized by single-crystal X-ray crystallography. The mononuclear complex has a highly distorted octahedral geometry. The tetranuclear Fe(III) complexes are found to be rare examples with discrete neutral alkoxido-oxido clusters with Fe-4(III)(mu(4)-0) cores. (C) 2013 Elsevier B.V. All rights reserved.
DOI http://dx.doi.org/10.1016/j.molstruc.2013.02.035
ISBN
Publisher
Book Title
ISSN 0022-2860
EISSN
Conference Name
Bibtex ID ISI:000319176700007
Observations
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