Publication Type Journal Article
Title Erbium-Doped Tin-Silicate Sol-Gel-Derived Glass-Ceramic Thin Films: Effect of Environment Segregation on the Er3+ Emission
Authors Tran T. T. Van S. Turrell B. Capoen Lam Q. Vinh O. Cristini-Robbe M. Bouazaoui F. d Acapito M. Ferrari D. Ristic A. Lukowiak Rui M. Almeida L. F. Santos C. Kinowski
Groups
Journal SCIENCE OF ADVANCED MATERIALS
Year 2015
Month February
Volume 7
Number 2
Pages 301-308
Abstract A new class of glass-ceramic nanocomposite systems with a uniform distribution of SnO2 nanocrystals dispersed within an amorphous silica phase is fabricated in the form of thin films by using sol gel processing. In this work, experiments with (100-x)SiO2-xSnO(2) nanocomposite thin films with (x=25 and 30 mol\%) doped with Er3+ ions (concentrations of 0.5, 1 and 2 mol\%) are presented. The focus has been both to determine the effect of rare-earth doping on the growth of SnO2 nanocrystals as well as the distribution of the Er3+ ions within the ceramic structure. Vibrational spectroscopic assessments have proven the glass-ceramic nature of the samples. EXAFS and photoluminescence spectra show that the rare-earth ions exist in both amorphous and crystalline phases. Moreover an energy transfer from SnO2 nanocrystals to erbium ions on excitation at 351 nm is demonstrated.
DOI http://dx.doi.org/10.1166/sam.2015.2022
ISBN
Publisher
Book Title
ISSN 1947-2935
EISSN 1947-2943
Conference Name
Bibtex ID ISI:000349140700015
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