Publication Type |
Journal Article |
Title |
Cyanosilylation of Aldehydes Catalyzed by Iron(III) Arylhydrazone-beta-Diketone Complexes |
Authors |
Atash V. Gurbanov Abel M. Maharramov Fedor I. Zubkov Alexander M. Saifutdinov Firudin I. Guseinov |
Groups |
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Journal |
AUSTRALIAN JOURNAL OF CHEMISTRY |
Year |
2018 |
Month |
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|
Volume |
71 |
Number |
2 |
Pages |
190-194 |
Abstract |
Two known iron(III) complexes, [Fe(H2O)(3)(L-1)]center dot xH(2)O (x = 4 (1), 5 (2)) and [Fe(H2O)(3)(L-2)]center dot 3H(2)O (3), bearing the basic forms of 5-chloro-3-(2-(4,4-dimethyl-2,6-dioxocyclohexylidene)hydrazinyl)-2-hydro xybenzenesulfonic acid (H3L1) and 3-(2-(2,4-dioxopentan-3-ylidene) hydrazinyl)-2-hydroxy-5-nitrobenzenesulfonic acid (H3L2), were prepared and used as homogeneous catalysts for cyanosilylation of a variety of aldehydes with trimethylsilyl cyanide leading to the corresponding cyanohydrin trimethylsilyl ethers. High yield (up to 98 \%) was observed in the reaction catalyzed by 3 at room temperature in methanol. |
DOI |
http://dx.doi.org/10.1071/CH17595 |
ISBN |
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Publisher |
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Book Title |
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ISSN |
0004-9425 |
EISSN |
1445-0038 |
Conference Name |
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Bibtex ID |
ISI:000426369100016 |
Observations |
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