Publication Type Journal Article
Title Cyanosilylation of Aldehydes Catalyzed by Iron(III) Arylhydrazone-beta-Diketone Complexes
Authors Atash V. Gurbanov Abel M. Maharramov Fedor I. Zubkov Alexander M. Saifutdinov Firudin I. Guseinov
Groups
Journal AUSTRALIAN JOURNAL OF CHEMISTRY
Year 2018
Month
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Volume 71
Number 2
Pages 190-194
Abstract Two known iron(III) complexes, [Fe(H2O)(3)(L-1)]center dot xH(2)O (x = 4 (1), 5 (2)) and [Fe(H2O)(3)(L-2)]center dot 3H(2)O (3), bearing the basic forms of 5-chloro-3-(2-(4,4-dimethyl-2,6-dioxocyclohexylidene)hydrazinyl)-2-hydro xybenzenesulfonic acid (H3L1) and 3-(2-(2,4-dioxopentan-3-ylidene) hydrazinyl)-2-hydroxy-5-nitrobenzenesulfonic acid (H3L2), were prepared and used as homogeneous catalysts for cyanosilylation of a variety of aldehydes with trimethylsilyl cyanide leading to the corresponding cyanohydrin trimethylsilyl ethers. High yield (up to 98 \%) was observed in the reaction catalyzed by 3 at room temperature in methanol.
DOI http://dx.doi.org/10.1071/CH17595
ISBN
Publisher
Book Title
ISSN 0004-9425
EISSN 1445-0038
Conference Name
Bibtex ID ISI:000426369100016
Observations
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