Publication Type Journal Article
Title New Trendy Magnetic C-Scorpionate Iron Catalyst and Its Performance towards Cyclohexane Oxidation
Authors A.P.C. Ribeiro Ines A.S. Matias Elisabete C.B.A. Alegria Ana M. Ferraria Ana M. Botelho do Rego Armando J.L. Pombeiro L.M.D.R.S. Martins
Groups CCC
Journal CATALYSTS
Year 2018
Month February
Volume 8
Number 2
Pages
Abstract For the first time, a magnetic C-scorpionate catalyst was prepared from the iron(II) complex [FeCl2\kappa(3)-HC(pz)(3)\] (pz = pyrazol-1-yl) and ferrite, using the sustainable mechanochemical synthetic procedure. Its catalytic activity for the cyclohexane oxidation with tert-butyl hydroperoxide (TBHP) was evaluated in different conditions, namely under microwave irradiation and under the effect of an external magnetic field. The use of such magnetic conditions significantly shifted the catalyst alcohol/ketone selectivity, thus revealing a promising, easy new protocol for tuning selectivity in important catalytic processes.
DOI http://dx.doi.org/10.3390/catal8020069
ISBN
Publisher
Book Title
ISSN 2073-4344
EISSN
Conference Name
Bibtex ID ISI:000427512900028
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