Publication Type Journal Article
Title Layered europium hydroxide system for phosphorous sensing and remediation
Authors Claudia C. L. Pereira Joao C. Lima Artur J. Moro Bernardo Monteiro
Groups IOARC
Journal APPLIED CLAY SCIENCE
Year 2017
Month September
Volume 146
Number
Pages 216-222
Abstract A Layered Lanthanide Hydroxide (LLH) material based on europium (LEuH, Eu-8(OH)(20)Cl(4.)6H(2)O) was intercalated with 2,6-naphtalenedicarboxylate (NDC) yielding a material presenting the bright red luminescence characteristic of Eu3+, both by direct excitation of europium and energy transfer from NDC. The material behaves as a sensor towards anions which display the ability to exchange with NDC. The sensor was tested with several anions (phosphate, sulphate, pyrophosphate, acetate, and tetraborate anions) and the changes in NDC (lambda(em) = 380 nm) and europium (lambda(em) = 615 nm) emission intensities upon excitation of NDC (lambda(ex) = 357 nm), were studied. Phosphate was found to have the highest degree of intercalation and displayed a strong increase (400\% fold) on the fluorescence intensity of NDC. The presence of phosphate was further confirmed with Inductively Coupled Plasma-Atomic Emission Spectrometer (ICP-AES). Taking advantage of LEuH selectivity towards phosphate, its applicability in phosphorus remediation was studied presenting high sequestration capacity followed by controlled release of phosphate in three consecutive cycles and improved stability of the LEuH host material. These results highlight the significant potential of LLHs as new scavenging agents for inorganic phosphate.
DOI http://dx.doi.org/10.1016/j.clay.2017.06.002
ISBN
Publisher
Book Title
ISSN 0169-1317
EISSN 1872-9053
Conference Name
Bibtex ID ISI:000407655000028
Observations
Back to Publications List