| Publication Type |
Journal Article |
| Title |
Solvent effects on solution enthalpies of adamantyl derivatives |
| Authors |
F. Martins Luís Moreira N. G. C. Nunes R. Elvas-Leitão |
| Groups |
MET |
| Journal |
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY |
| Year |
2010 |
| Month |
May |
| Volume |
100 |
| Number |
2 |
| Pages |
483-491 |
| Abstract |
Solution enthalpies of 1-bromoadamantane, 1-adamantanol, and 2-adamantanone in a large set of protic and aprotic solvents are reported at 298.15 K. Solvent effects on the solution processes of these solutes are analyzed in terms of a modified TAKA equation, involving delta(cav) h (s) as the cavity term. The nature and magnitude of the major interactions which influence these processes are assessed and discussed in terms of the solutes characteristics. New insights on the solution processes under scrutiny are presented. |
| DOI |
http://dx.doi.org/10.1007/s10973-009-0651-x |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
1388-6150 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000276771600015 |
| Observations |
|
