Publication Type Journal Article
Title Synthesis of a mononuclear oxidovanadium(V) complex by bridge-splitting of the corresponding binuclear precursor
Authors Manas Sutradhar Tannistha Roy Barman Saktiprosad Ghosh Michael G. B. Drew
Groups CCC
Journal JOURNAL OF MOLECULAR STRUCTURE
Year 2012
Month August
Volume 1020
Number
Pages 148-152
Abstract The mononuclear oxidovanadium(V) complex VO(OEt)L (2), where L2- is the dianion of a diprotic tridentate ONO donor ligand, 2-hydroxyacetophenone-2-aminobenzoylhydrazone (H2L), has been synthesized by oxido-bridge splitting of the corresponding binuclear complex V2O3L2 (1) and structurally characterized by single crystal X-ray diffraction analysis, together with electrochemical and spectral studies. Splitting of the oxido-bridge was effected by refluxing 1 with excess triphenylphosphine in ethanol medium. The crystal structure of 2 is compared with that of the precursor binuclear complex 1. (C) 2012 Elsevier B.V. All rights reserved.
DOI http://dx.doi.org/10.1016/j.molstruc.2012.04.007
ISBN
Publisher
Book Title
ISSN 0022-2860
EISSN 1872-8014
Conference Name
Bibtex ID ISI:000306046500021
Observations
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