Publication Type |
Journal Article |
Title |
Synthesis of a mononuclear oxidovanadium(V) complex by bridge-splitting of the corresponding binuclear precursor |
Authors |
Manas Sutradhar Tannistha Roy Barman Saktiprosad Ghosh Michael G. B. Drew |
Groups |
CCC |
Journal |
JOURNAL OF MOLECULAR STRUCTURE |
Year |
2012 |
Month |
August |
Volume |
1020 |
Number |
|
Pages |
148-152 |
Abstract |
The mononuclear oxidovanadium(V) complex VO(OEt)L (2), where L2- is the dianion of a diprotic tridentate ONO donor ligand, 2-hydroxyacetophenone-2-aminobenzoylhydrazone (H2L), has been synthesized by oxido-bridge splitting of the corresponding binuclear complex V2O3L2 (1) and structurally characterized by single crystal X-ray diffraction analysis, together with electrochemical and spectral studies. Splitting of the oxido-bridge was effected by refluxing 1 with excess triphenylphosphine in ethanol medium. The crystal structure of 2 is compared with that of the precursor binuclear complex 1. (C) 2012 Elsevier B.V. All rights reserved. |
DOI |
http://dx.doi.org/10.1016/j.molstruc.2012.04.007 |
ISBN |
|
Publisher |
|
Book Title |
|
ISSN |
0022-2860 |
EISSN |
1872-8014 |
Conference Name |
|
Bibtex ID |
ISI:000306046500021 |
Observations |
|