| Publication Type |
Journal Article |
| Title |
Direct Reductive Deoxygenation of Aryl Ketones Catalyzed by Oxo-Rhenium Complexes |
| Authors |
Tiago A. Fernandes Joana R. Bernardo A C Fernandes |
| Groups |
BioMol |
| Journal |
CHEMCATCHEM |
| Year |
2015 |
| Month |
April |
| Volume |
7 |
| Number |
7 |
| Pages |
1177-1183 |
| Abstract |
The first methodology for the direct reductive deoxygenation of ketones catalyzed by high-valent oxo-rhenium complexes by using a silane as reducing agent is described. The systems PhSiH3/[ReOCl3(SMe2)(OPPh3)] (2mmol/5mol\%) and PhSiH3/[ReOCl3(PPh3)(2)] (2mmol/5mol\%) proved to be efficient for the deoxygenation of aryl ketones, producing selectively the corresponding alkane, or a mixture of alkane and alkene derivatives with the alkane as the major product. |
| DOI |
http://dx.doi.org/10.1002/cctc.201402909 |
| ISBN |
|
| Publisher |
WILEY-V C H VERLAG GMBH |
| Book Title |
|
| ISSN |
1867-3880 |
| EISSN |
1867-3899 |
| Conference Name |
|
| Bibtex ID |
ISI:000352488300018 |
| Observations |
|
