| Publication Type |
Journal Article |
| Title |
Energetic characterisation of the system (water+1-propoxypropan-2-ol) at T=298.15 K |
| Authors |
M. L. C. J. Moita Marina C. Reis A.F. Santos Isabel M. S. Lampreia |
| Groups |
MTFT MET |
| Journal |
JOURNAL OF CHEMICAL THERMODYNAMICS |
| Year |
2015 |
| Month |
December |
| Volume |
91 |
| Number |
|
| Pages |
172-176 |
| Abstract |
Given the importance that enthalpic and entropic contributions have in the interplay between thermodynamics and self-assembly of aqueous amphiphile systems, the energetic characterisation of the system \water + 1-propoxypropan-2-ol (1-pp-2-ol)\ at T = 298.15 K was made by directly measuring excess partial molar enthalpies of 1-pp-2-ol and water, over the entire composition range, at T = 298.15 K and atmospheric pressure. Derivatives of the partial molar properties with respect to the composition are used to improve the understanding of molecular interactions in the water-rich region. The present results were compared with those for the well-studied system \water + 2-butoxyethanol (nC(4)E(1))\, the two amphiphiles being structural isomers. (C) 2015 Elsevier Ltd. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/j.jct.2015.07.044 |
| ISBN |
|
| Publisher |
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD |
| Book Title |
|
| ISSN |
0021-9614 |
| EISSN |
1096-3626 |
| Conference Name |
|
| Bibtex ID |
ISI:000361472600022 |
| Observations |
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