Publication Type Journal Article
Title Metal-Organic Frameworks with Pyridyl-Based Isophthalic Acid and Their Catalytic Applications in Microwave Assisted Peroxidative Oxidation of Alcohols and Henry Reaction
Authors Anirban Karmakar L.M.D.R.S. Martins Susanta Hazra M. Fátima C. Guedes da Silva Armando J.L. Pombeiro
Groups CCC
Journal CRYSTAL GROWTH \& DESIGN
Year 2016
Month April
Volume 16
Number 4
Pages 1837-1849
Abstract Reactions of 5-\(pyridin-4-ylmethyl)amino\ isophthalic acid (H(2)L1) with copper(II), zinc(II), and cadmium(II) were studied, and the obtained metal organic frameworks (MOFs) [\Cu(L1)(DMF)\center dot DMF center dot H2O](n) (1), [Zn(L1)(H2O)(n) (2), and [Cd(L1)](n) (3) were characterized by elemental analysis, Fourier transform infrared spectroscopy, and X-ray single-crystal diffraction. As shown by X-ray crystallography, novel hybrid organic inorganic coordination-driven assemblies were obtained which exhibit different two- and three-dimensional (2D and 3D) polymeric architectures. Compounds 1 and 2 have 2D structures, whereas compound 3 features a 3D network type polymer with a dimetallic core acting as a secondary building unit. These frameworks act as heterogeneous polymeric solid catalysts (the most effective one being the copper MOF 1) for solvent-free microwave assisted peroxidative oxidation of primary and secondary alcohols. They also effectively catalyze the nitroaldol (Henry) reaction of different aldehydes with nitroalkanes in water. These MOF-based heterogeneous catalysts can be easily recovered and reused, at least for a few consecutive cycles, without losing activity.
DOI http://dx.doi.org/10.1021/acs.cgd.5b01178
ISBN
Publisher AMER CHEMICAL SOC
Book Title
ISSN 1528-7483
EISSN 1528-7505
Conference Name
Bibtex ID ISI:000373747700010
Observations
Back to Publications List