| Publication Type |
Journal Article |
| Title |
Diaquabis(propane-1,3-diamine)copper(II) bis[diamminetetrakis(thiocyanato-kappa N)chromate(III)] dimethyl sulfoxide octasolvate |
| Authors |
Vitalina M. Nikitina Oksana V. Nesterova Roman I. Zubatyuk Oleg V. Shishkin Julia A. Rusanova |
| Groups |
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| Journal |
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Year |
2011 |
| Month |
July |
| Volume |
67 |
| Number |
7 |
| Pages |
M849-U358 |
| Abstract |
The ionic title complex, [Cu(C3H10N2)(2)(H2O)(2)][Cr(NCS)(4)(NH3)(2)]center dot 8C(2)H(6)OS, consists of complex [Cu(dipr)(2)(H2O)(2)](2+) copper cations (dipr is propane-1,3-diamine), complex [Cr(NCS)(4)(NH3)(2)](-) anions and uncoordinated solvent dimethyl sulfoxide (DMSO) molecules. All the metal atoms lie on crystallographic centers of symmetry. The cations are connected to the anions through N-H center dot center dot center dot O hydrogen bonds between the NH3 molecules of the anion and the water molecules of the cation. The DMSO molecules are involved in hydrogen-bonded linkage of the [Cr(NCS)(4)(NH3)(2)](-) anions into supramolecular chains through bridging O atoms. A network of hydrogen bonds as well as short S center dot center dot center dot S contacts [3.5159 (12) and 3.4880 (12) angstrom] between the NCS groups of the complex anions link the molecules into a three-dimensional supramolecular network. |
| DOI |
http://dx.doi.org/10.1107/S160053681102023X |
| ISBN |
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| Publisher |
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| Book Title |
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| ISSN |
1600-5368 |
| EISSN |
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| Conference Name |
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| Bibtex ID |
ISI:000294663000021 |
| Observations |
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