| Publication Type |
Journal Article |
| Title |
Sodium- and chloride-selective microelectrodes optimized for corrosion studies |
| Authors |
Valentine A. Nazarov Maryna Taryba Elena A. Zdrachek Kseniya A. Andronclayk Vladimir V. Egorov Svetlana V. Lamaka |
| Groups |
|
| Journal |
JOURNAL OF ELECTROANALYTICAL CHEMISTRY |
| Year |
2013 |
| Month |
October |
| Volume |
706 |
| Number |
|
| Pages |
13-24 |
| Abstract |
New sodium and chloride ion-selective membrane cocktails for glass-capillary microelectrodes were developed satisfying the demands for corrosion studies. Membrane cocktails were optimized to provide a wide pH working range, good long-term stability and reproducibility of potential. The proposed sodium-selective cocktail contains sodium ionophore VI, potassium tetrakis(4-chlorophenyl) borate and 2-nitrophenyl octyl ether. The chloride-selective cocktail consists of tridodecylmethylammonium chloride and 2-nitrophenyl octyl ether. The proposed microelectrodes were successfully applied to measure the concentration of Cl- and Na+ over corroding cut-edge samples of metallic coated steel and can be recommended for measuring the distribution of Na+ and Cl- in corrosion applications. (C) 2013 Elsevier B.V. All rights reserved. |
| DOI |
http://dx.doi.org/10.1016/j.jelechem.2013.07.034 |
| ISBN |
|
| Publisher |
|
| Book Title |
|
| ISSN |
1572-6657 |
| EISSN |
1873-2569 |
| Conference Name |
|
| Bibtex ID |
ISI:000328096200003 |
| Observations |
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