| Publication Type |
Journal Article |
| Title |
How similar is similar? Exploring the binary and ternary solid solution landscapes of p-methyl/chloro/bromo-benzyl alcohols |
| Authors |
A. K. S. Romasanta D. Braga M. Teresa Duarte F. Grepioni |
| Groups |
|
| Journal |
CRYSTENGCOMM |
| Year |
2017 |
| Month |
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|
| Volume |
19 |
| Number |
4 |
| Pages |
653-660 |
| Abstract |
New binary and ternary solid solutions formed by p-chlorobenzyl alcohol (p-ClBA), p-bromobenzyl alcohol (p-BrBA) and their quasi-isostructural compound p-methylbenzyl alcohol (p-MeBA) have been prepared and characterized by DSC and powder X-ray diffraction. The binary and ternary solid solutions were synthesized by co-melting of p-MeBA/p-ClBA, p-MeBA/p-BrBA and p-ClBA/p-BrBA and by co-melting of p-MeBA/p-ClBA/p-BrBA in various molar ratios. By varying the relative concentrations, it has been possible to observe the consequent variations of the melting points of the solid solutions. For the binary 1:1 p-MeBA/p-BrBA and p-ClBA/p-BrBA compounds, single crystals were grown from solution and their structures were investigated by X-ray diffraction. |
| DOI |
http://dx.doi.org/10.1039/c6ce02282k |
| ISBN |
|
| Publisher |
ROYAL SOC CHEMISTRY |
| Book Title |
|
| ISSN |
1466-8033 |
| EISSN |
|
| Conference Name |
|
| Bibtex ID |
ISI:000395439700008 |
| Observations |
|
