| Publication Type |
Journal Article |
| Title |
Hydrogen bonds between methanol and the light liquid olefins 1-pentene and 1-hexene: from application to fundamental science |
| Authors |
Zhaoxi Zhang Tiancun Xiao Hamid Al-Megren Saud A. Aldrees Mohammad Al-Kinany Vladimir L. Kuznetsov Maxim L. Kuznetsov Peter P. Edwards |
| Groups |
CCC |
| Journal |
CHEMICAL COMMUNICATIONS |
| Year |
2017 |
| Month |
April |
| Volume |
53 |
| Number |
28 |
| Pages |
4026-4029 |
| Abstract |
We have recently developed a new extraction process for significantly reducing the olefin content in commercial FCC gasoline. To gain insights into the origins of this process, we have investigated the dissolution of the light liquid olefins 1-pentene and 1-hexene in methanol through computer modelling together with NMR spectroscopy. We find two important hydrogen bonding modes for methanol olefin interactions - namely, O-H center dot center dot center dot pi and C-H center dot center dot center dot O. |
| DOI |
http://dx.doi.org/10.1039/c6cc09545c |
| ISBN |
|
| Publisher |
ROYAL SOC CHEMISTRY |
| Book Title |
|
| ISSN |
1359-7345 |
| EISSN |
1364-548X |
| Conference Name |
|
| Bibtex ID |
ISI:000399727100027 |
| Observations |
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